What would happen if you increased the temperature of a system that contained nitrogen, hydrogen, and ammonia? According to Le Châtelier's principle, if you added heat to the system, the equilibrium would shift in the direction that removes heat from the system. The system would favor the reverse reaction, which is endothermic. So by increasing the temperature, you would decrease the amount of ammonia.

Pressure

Suppose you increased the pressure of the system. According to Le Châtelier's principle, if you increased the pressure, the equilibrium would shift in the direction that decreases the pressure of the system. In order to decrease pressure, the system would favor the reaction that produces fewer gas molecules. You can see that the left side of the equation has four gas molecules, while the right side has two. So by increasing the pressure, you would shift the equilibrium to the right, producing more ammonia.

Concentration

A change in concentration of the reactants or products can also affect equilibrium. Suppose you removed ammonia from the nitrogen-hydrogen-ammonia system. Le Châtelier's principle tells you that the equilibrium would shift in the direction that produces ammonia. In order to produce ammonia, the system would favor the forward reaction.

Figure 27 Operating an ammonia plant at relatively low temperature, high pressure, and low ammonia concentration maximizes the amount of ammonia produced.

An aerial view of an industrial plant. The towers of the plant emit smoke into the air.

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Table of Contents

Physical Science CHAPTER 1 Science Skills CHAPTER 2 Properties of Matter CHAPTER 3 States of Matter CHAPTER 4 Atomic Structure CHAPTER 5 The Periodic Table CHAPTER 6 Chemical Bonds CHAPTER 7 Chemical Reactions CHAPTER 8 Solutions, Acids, and Bases CHAPTER 9 Carbon Chemistry CHAPTER 10 Nuclear Chemistry CHAPTER 11 Motion CHAPTER 12 Forces and Motion CHAPTER 13 Forces in Fluids CHAPTER 14 Work, Power, and Machines CHAPTER 15 Energy CHAPTER 16 Thermal Energy and Heat CHAPTER 17 Mechanical Waves and Sound CHAPTER 18 The Electromagnetic Spectrum and Light CHAPTER 19 Optics CHAPTER 20 Electricity CHAPTER 21 Magnetism CHAPTER 22 Earth's Interior CHAPTER 23 Earth's Surface CHAPTER 24 Weather and Climate CHAPTER 25 The Solar System CHAPTER 26 Exploring the Universe Skills and Reference Handbook