Robert Boyle, who was born in Ireland in 1627, was the first to describe the relationship between the pressure and volume of a gas. The graph in Figure 13 shows what happens when the volume of a cylinder containing a set amount of gas is decreased. What happens when the volume of the cylinder is reduced from 2.0 liters to 1.0 liter? The pressure of the gas in the cylinder doubles from 50 kilopascals to 100 kilopascals.
Boyle's law states that the volume of a gas is inversely proportional to its pressure if the temperature and the number of particles are constant. Boyle's law can be expressed mathematically. P1 and V1 represent the pressure and volume of a gas before a change occurs. P2 and V2 represent the pressure and volume of a gas after a change occurs.
How is Boyle's law expressed mathematically?
Observing the Effect of Temperature on Gas Pressure
Materials
pan, metric ruler, empty beverage can, masking tape, hot plate, clock, tongs
Procedure
Fill a pan with cold water to a depth of 3 cm.
Use masking tape to cover half the opening of the can. CAUTION Do not cover the entire opening with tape.
Place the can on the hot plate and turn the hot plate to a high setting. Heat the can for 5 minutes and then turn off the hot plate.
Use tongs to remove the can from the hot plate and place it upside down in the pan of water as shown. The opening should be below the surface of the water. Observe the can as it cools.
Analyze and Conclude
Inferring How did the temperature of the air inside the can change when you heated the can? How did it change when you put the can in the water?
Drawing Conclusions What happened to the pressure of the air inside the can when you put the can in the cold water?
Inferring Did the air pressure outside the can change during the experiment?
Formulating Hypotheses What caused the change you observed in Step 4?