Measuring Heat Changes

A calorimeter is an instrument used to measure changes in thermal energy. A calorimeter uses the principle that heat flows from a hotter object to a colder object until both reach the same temperature. According to the law of conservation of energy, the thermal energy released by a test sample is equal to the thermal energy absorbed by its surroundings. The calorimeter is sealed to prevent thermal energy from escaping.

Figure 4 shows how a calorimeter can be used to measure the specific heat of aluminum. A known mass of water is added to the calorimeter. The mass of the sample of aluminum is measured. The aluminum is heated and then placed in the water. The calorimeter is sealed. As the aluminum cools off, the water is stirred to distribute thermal energy evenly. The water heats up until both the aluminum and the water are at the same temperature. The change in temperature of the water is measured. The thermal energy absorbed by the water is calculated using the specific heat equation. Since this same amount of thermal energy was given off by the sample of aluminum, the specific heat of aluminum can be calculated.

A calorimeter with a section of the wall removed to show an aluminum sample cube inside. The calorimeter is filled with water and a thermometer and a stirrer are inserted in it.

Figure 4 A calorimeter is used to measure specific heat. A sample to be tested is heated and placed in the calorimeter. The lid is put on and the temperature change is observed. Hypothesizing Why does the calorimeter need a stirrer?


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Table of Contents

Physical Science CHAPTER 1 Science Skills CHAPTER 2 Properties of Matter CHAPTER 3 States of Matter CHAPTER 4 Atomic Structure CHAPTER 5 The Periodic Table CHAPTER 6 Chemical Bonds CHAPTER 7 Chemical Reactions CHAPTER 8 Solutions, Acids, and Bases CHAPTER 9 Carbon Chemistry CHAPTER 10 Nuclear Chemistry CHAPTER 11 Motion CHAPTER 12 Forces and Motion CHAPTER 13 Forces in Fluids CHAPTER 14 Work, Power, and Machines CHAPTER 15 Energy CHAPTER 16 Thermal Energy and Heat CHAPTER 17 Mechanical Waves and Sound CHAPTER 18 The Electromagnetic Spectrum and Light CHAPTER 19 Optics CHAPTER 20 Electricity CHAPTER 21 Magnetism CHAPTER 22 Earth's Interior CHAPTER 23 Earth's Surface CHAPTER 24 Weather and Climate CHAPTER 25 The Solar System CHAPTER 26 Exploring the Universe Skills and Reference Handbook