Figure 16 A gymnast on a balance beam is like an atom in an excited state—not very stable.
How are the seats in your classroom arranged? Are they lined up neatly in rows, or are they grouped in clusters? A configuration is an arrangement of objects in a given space. Some configurations are more stable than others, meaning that they are less likely to change. The position of the gymnast on the balance beam in Figure 16 is not very stable because the beam is only 10 centimeters wide.
An electron configuration is the arrangement of electrons in the orbitals of an atom. The most stable electron configuration is the one in which the electrons are in orbitals with the lowest possible energies. When all the electrons in an atom have the lowest possible energies, the atom is said to be in its ground state.
For example, lithium is a silvery-white metal with an atomic number of 3, which means that a lithium atom has three electrons. In the ground state, two of the lithium electrons are in the orbital of the first energy level. The third electron is in an orbital of the second energy level.
If a lithium atom absorbs enough energy, one of its electrons can move to an orbital with a higher energy. This configuration is referred to as an excited state. An excited state is less stable than the ground state. Eventually, the electron that was promoted to a higher energy level loses energy, and the atom returns to the ground state. Helium, neon, argon, krypton, and xenon atoms returning from excited states to the ground state emit the light you see in “neon” lights.
Reviewing Concepts
When is an electron in an atom likely to move from one energy level to another?
What model do scientists use to describe how electrons move around the nucleus?
Describe the most stable configuration of the electrons in an atom.
What did Bohr contribute to modern atomic theory?
What does an electron cloud represent?
Critical Thinking
Comparing and Contrasting A boron atom has two electrons in the first energy level and three in the second energy level. Compare the relative energies of the electrons in these two energy levels.
Making Judgments Was Rutherford's model of an atom incorrect or incomplete? Explain your answer.
Posing Questions Apply what you know about charged particles to the modern model of the atom. Is there anything about the behavior of electrons in atoms that is unexpected? Explain your answer.