Unsaturated Hydrocarbons

A hydrocarbon that contains one or more double or triple bonds is an unsaturated hydrocarbon. These hydrocarbons are classified by bond type and the arrangement of their carbon atoms. There are three types of unsaturated hydrocarbons—alkenes, alkynes, and aromatic hydrocarbons.

Diagram of three types of unsaturated hydrocarbons. On the left is the bond for ethene. In the middle is the bond for ethyne. On the right is the bond for benzene.

Alkenes

Many fruit-bearing plants produce ethene (C2H4), which controls the rate at which fruits, such as the tomato in Figure 6A, ripen. There is a double bond between the two carbon atoms in ethene. Hydrocarbons that have one or more carbon-carbon double bonds are alkenes. The names of alkenes end in −ene. Plastics used in trash bags and milk jugs are produced by reactions involving ethene.

Figure 6 There are three types of unsaturated hydrocarbons. A Ethene is an alkene that controls the ripening of a tomato. B Ethyne is an alkyne used in torches that cut metals or weld them together. C Kekulé figured out the ring structure of the aromatic hydrocarbon benzene.

A set of three images, one of a ripe tomato, the next of a man welding with metal as sparks fly, and the third a portrait of Kekule on a stamp.
Alkynes

In 1895, Henry-Louis Le Châtelier reported that a flame produced when ethyne burned had a temperature about 1000°C higher than a flame produced when hydrogen burns. Ethyne (C2H2), also known as acetylene, is an alkyne. Alkynes are straight- or branched-chain hydrocarbons that have one or more triple bonds. Alkyne names end in −yne.

Alkynes are the most reactive hydrocarbon compounds. The welder in Figure 6B is burning a mixture of oxygen and acetylene in an oxyacetylene torch. The temperature of the flame produced approaches 3500°C. At that temperature, most metals can be melted and welded together. The acetylene and oxygen are stored under pressure in tanks.

Aromatic Hydrocarbons

The Belgian stamp in Figure 6C honors Friedrich Kekulé (1829−1896), who figured out that benzene (C6H6) is an unsaturated hydrocarbon with a ring structure. Although the formula shows alternating single and double bonds, the six bonds in the ring are identical. Six of the valence electrons are shared by all six carbon atoms. Hydrocarbons that contain similar ring structures are known as aromatic hydrocarbons. The name was chosen because many of these compounds have strong aromas or odors.


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Table of Contents

Physical Science CHAPTER 1 Science Skills CHAPTER 2 Properties of Matter CHAPTER 3 States of Matter CHAPTER 4 Atomic Structure CHAPTER 5 The Periodic Table CHAPTER 6 Chemical Bonds CHAPTER 7 Chemical Reactions CHAPTER 8 Solutions, Acids, and Bases CHAPTER 9 Carbon Chemistry CHAPTER 10 Nuclear Chemistry CHAPTER 11 Motion CHAPTER 12 Forces and Motion CHAPTER 13 Forces in Fluids CHAPTER 14 Work, Power, and Machines CHAPTER 15 Energy CHAPTER 16 Thermal Energy and Heat CHAPTER 17 Mechanical Waves and Sound CHAPTER 18 The Electromagnetic Spectrum and Light CHAPTER 19 Optics CHAPTER 20 Electricity CHAPTER 21 Magnetism CHAPTER 22 Earth's Interior CHAPTER 23 Earth's Surface CHAPTER 24 Weather and Climate CHAPTER 25 The Solar System CHAPTER 26 Exploring the Universe Skills and Reference Handbook